Product ID:BLACK URETHANE SUB, PART B, 13911
MSDS Date:10/21/1996
FSC:8010
NIIN:01-380-3257
Status Code:A
Kit Part:Y
MSDS Number: CLHXM

FINNAREN & HALEY INC

901 WASHINGTON ST
CONSHOHOCKEN, PA 19428
US

Emergency Phone: (800)424-9300

Info Phone: 1-610-825-1900

Preparer: HENRY SIMMONS

Cage: 9V982

FINNAREN & HALEY INC

CONSHOHOCKEN, PA 19428 US

Telephone: 1-610-825-1900

Cage: 9V982

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.034 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

AROMATIC 100 (SOLVENT NAPHTHA)

CAS: 64742-95-6

RTECS: WF3400000

N-BUTYL ACETATE

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE INHALATION: HDI VAPORS OR MIST
AT CONCENTRATION ABOVE THE TLV CAN IRRITATE (BURNING SENSATION) THE
MUCOUS MEMBRANES IN THE RESPIRATORY TRACT (NOSE, THROAT, LUNGS)
CAUSING RUNNING NOSE, SORE THRO AT, COUGHING, CHEST DISCOMFORT,
SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION.CHRONIC INHALATION:
AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE
DOSE, CERTAIN INDIVIDUALS WILL DEVELO P ISOCYANATE SENSITIZATION
(CHEMICAL ASTHMA) WHICH WILL CAUSE THEM TO REACT TO A LATER
EXPOSURES TO ISOCYANATE AT LEVELS WELL BELOW THE TLV.ACUTE SKIN
CONTACT: ISOCYANATES REACT WITH SKIN PROTEIN AND MOISTURE AND CAN
CAUSE IRRITATION. CHRO
Effects of Overexposure:ACUTE: ISOCYANATES REACT WITH SKIN PROTEIN AND
CAN CAUSE IRRITATION. CHRONIC: ISOCYANATE CAN CAUSE REDDENING,
SWELLING, RASH, SCALING OR BLISTERING. ACUTE EYE CONTACT:
IRRITATING AND CAN CAUSE TEARING , REDDENING AND SWELLING
ACCOMPANIED BY A STINGING SENSATION. CHRONIC EYE CONTACT: (CLOUDING
OF THE EYE SURFACE) PROLONGED VAPOR CONTACT MAY CAUSE
CONJUNCTIVITIS. ACUTE INGESTION: IRRITATION AND POSSI BLE ACTION IN
THE MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERACTIVITY), SKIN ALLERGIES,
ECZEMA.

First Aid:EYES-FLUSH WITH CLEAN, LUKEWARM WATER (LOW PRESSURE) FOR AT
LEAST 15 MINUTES, WHILE LIFTING EYELIDS. REFER INDIVIDUAL TO A
PHYSICIAN OR OPHTHALMOLOGIST FOR IMMEDIATE FOLLOW-UP. SKIN-REMOVE
CONTAMINAT ED CLOTHING IMMEDIATELY. WASH AFFECTED AREAS THOROUGHLY
WITH SOAP AND WATER. WASH CONTAMINATED CLOTHING THOROUGHLY BEFORE
REUSE. INHALATION-MOVE TO AN AREA FROM RISK OF FURTHER EXPOSURE.
ADMINISTER O XYGEN OR ARTIFICIAL RESPIRATION AS NEEDED.
INGESTION-DO NOT INDUCE VOMITING. GIVE 1-2 CUPS OF MILK OR WATER TO
DRINK. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR
CONVULSING PERSON. CONSULT PHY SICIAN.

Flash Point Method:SCC
Flash Point:=48.3C, 119.F
Lower Limits:1.2
Upper Limits:7.5
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY FOR
LARGE FIRES.
Fire Fighting Procedures:FULL EMERGENCY EQUIPMENT WITH SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD BE WORN BY
FIRE FIGHTERS. DURING A FIRE, HDI VAPORS AND OTHER IRRITATING;
HIGHLY TOXIC GASES MAY B E GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION. CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT.

Spill Release Procedures:EVACUATE NONESSENTIAL PERSONNEL. REMOVE ALL
SOURCES OF IGNITION AND VENTILATE THE AREA. NOTIFY APPROPRIATE
AUTHORITIES IF NECESSARY. PUT ON PERSONAL PROTECTIVE EQUIPMENT (SEE
SECTION VII). DIKE OR IMP OUND SPILLED MATERIAL AND CONTROL FURTHER
SPILLAGE IF FEASIBLE. COVER THE SPILL WITH SAWDUST, VERMICULITE,
FULLER?S EARTH OR OTHER ABSORBENT MATERIAL.

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER TO
PREVENT MOISTURE CONTAMINATION. DO NOT RESEAL IF CONTAMINATION IS
SUSPECTED. AT MAXIMUM STORAGE TEMPERATURES (122F), MATERIAL MAY
SLOWLY POLYMERIZE WITHOUT HAZARD. IDEA STORAGE TEMPERATURE RANGE
FOR EASE OF HANDLING IS 50-81F (10-27C)).

Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN ISOCYANATE CONTAINING ENVIRONMENT (AIR PURIFYING OR FRESH
AIR SUPPLIED) MAY BE NECESSARY. CONSIDER TYPE OF APPLICATION AND
ENVIROMEMTAL CONCENTR ATIONS. OBSERVE OSHA REGULATOINS FOR
RESPIRATOR USE (29 CFR 1910.134).
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES, SPLASH GOGGLES OR FACE SHIELD.
Work Hygienic Practices:PRECAUTIONS MUST BE TAKEN THAT PERSONS HANDLING
THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT CONTACT THE EYE
OR SKIN.
Supplemental Safety and Health

Boiling Pt:=126.7C, 260.F
B.P. Text:260-392F
Vapor Pres:7.5 X 10-5 MM HG @ 20C
Spec Gravity:1.1 @ 68F (20C)
VOC Grams/Liter:9.2
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR/PALE YELLOW LIQUID AND SOLVENT ODOR
Percent Volatiles by Volume:21.4%

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, HCN, HDI.
Conditions to Avoid Polymerization:MAY OCCUR, CONTACT WITH MOISTURE OR
OTHER MATERIALS WHICH REACT WITH ISOCYANATES OR TEMPERATURE OVER
400F (204C) MAY CAUSE PO

Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
INCINERATION IS THE PREFERRED METHOD. EMPTY CONTAINERS MUST BE
HANDLED WITH CARE DUE TO PRODUCT RESIDUE. DECONTAMINATE CONTAINERS
PRIOR TO DISPOSAL. DO NOT HEAT OR CUT EMPTY CONTAINER WITH ELECTR
IC OR GAS TORCH.

Toxicological Information:ACUTE TOXICITY: ORAL LD50: ESTIMATED TO BE
GREATER THAN 10000 MG/KG (RATS) DERMAL LD50: ESTIMATED TO BE
GREATER THAN 5000 MG/KG (RABBITS) INHALATION LC50: LOWER
RESPIRATORY (PULMONARY) IRRITANT. LC 50 VALUE RANGE FROM 137-1150
MG/M3 WERE OBTAINED IN RATS EXPOSED TO AEROSOLS. (4H EXP.) SEVERE
IRRITANT CAPABLE OF INDUCING CORNEAL INJURY (RABBIT); MAXIMUM
PRIMARY EYE IRRITATION SCORE: 54.6/110 FOR A 24 HOUR.SKIN
EFFECTS:MODERATE AND DERMAL; PRIMARY DERMAL IRRITATION SCORE:
3.4/8.0 (RABBIT). PULMONARY AND DERMAL SENSITIZER IN ANIMALS AND
HUMAN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:AVOID DISCHARGE TO NATURAL WATERS.

SARA Title III Information:SECTION 311/312 IMMEDIATE HEALTH HAZARD;
DELAYED HEALTH HAZARD; REACTIVE HAZARD; FIRE HAZARD.
Federal Regulatory Information:RCRA STATUS: WHEN DISCARDED IN ITS
PURCHASED FORM, THUS PRODUCT MEET THE CRITERIA OF IGNITABILITY, AND
SHOULD BE MANGED AS A HAZARDOUS WASTE (EPA HAZARDOUS WASTE NUMBER
D001) (40 CFR 261.20-24)
State Regulatory Information:HOMOPOLYMER OF HDI 28182-81-2, 83%, PA,
NJ. AROMATIC 100 (SOLVENT NAPHTHA) (AR100) 64742-95-6, 4.6%, PA,
NJ. N-BUTYL ACETATE (BA) 123-86-4, 4.6%, PA, MA, NJ. ACETATATE
ESTER 90438-79-2, 7.8%, PA, NJ. CALIFORNIA PROPOSITION 65 TO THE
BEST OF OUR KNOWLEDGE, THIS PRODUCT CONTAINS NO LEVELS OF LISTED
SUBSTANCES, WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTI VE EFFECTS.